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grade 12 Chemistry review

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  • If n=2, what is l and ml respectively?
    l = 0, 1; ml= -1, 0, +1
  • The oxidation number of N in (NH4)3PO4 (ammonium phosphate) is:
    -3
  • The pH at the equivalence point of a titration of a weak acid with a strong base will approximately be
    greater than 7.00
  • Which one of the following is a redox reaction?
    CaBr2 (aq) + H2SO4 (aq) → CaSO4 (s) + 2HBr(g)
    2KBr(aq) + Pb(NO3 )2 (aq) → 2KNO3 (aq) + PbBr2 (s)
    H+ (aq) + OH– (aq) → H2O(l)
    2Al(s) + 3H2SO4 (aq) → Al2 (SO4 )3 (aq) + 3H2 (g)
  • What is the hybridization of a carbon in ethene?
    sp2
  • How many carbons are there in 3-ethylpentane?
    7
  • In the following chemical reaction the oxidizing agent is 1. 5H2O2 + 2MnO4 – + 6H+ → 2Mn2+ + 8H2O + 5O2
    MnO4 –
  • Is cyclopentanol a primary secondary or tertiary alcohol?
    secondary alcohol ( 2 carbons attached to the adjacent carbon of alcohol)
  • The air pollutant NO is produced in automobile engines from the high temperature reaction: N2 (g) + O2 (g) D 2NO(g) Keq = 1.7 x 10-3 at 2300K. If the initial concentration of N2 (g) and O2 (g) at 2300K are both 1.40M, what is the concent
    1.372 mol/L
  • Identify the reducing agent in the following chemical reaction. Cd + NiO2 + 2H2O → Cd(OH)2 + Ni(OH)2
    Cd
  • How can you convert but-2-yne to (2Z)-but-2-ene
    specifically a Lindlar hydrogenation (converts to cis configuration)
  • What is the specific heat capacity of zinc if it requires 146 J to raise the temperature of 15 grams of zinc by 25°C?
    0.39 J/g°C
  • Cyclopropane undergoes rearrangement to form propene, C3H6. If cyclopropane disappears at a rate of 0.50 mol/ Ls, at what rate is propene being pduced?ro
    rate of appearance = +0.50 mol/Ls
  • What is the correct electronic configuration of Copper?
    [Ar]4s13d10
  • Calculate the [H+] in a solution that is 0.18 M in NaF and 0.25 M in HF. (Ka = 7.2 × 10–4)
    1.0 × 10–3 M
  • What is the VSEPR shape of AsH3
    trigonal pyramidal (AX3E)
  • The oxidation number of Fe in K3Fe(CN)6 is:
    +3
  • What is the pH of a solution made of 0.50 M acetic acid and 0.200 sodium acetate given the Ka of acetic acid is 1.8 x 10-5?
    4.34
  • Which of the following would you expect to have the highest boiling point? ethanol, ethyl ethanoate, ethanoic acid, ethane, ethene, ethyne, ethanal or chloroethane?
    ethanoic acid
    fluoroethane
    ethanal
    ethanol
  • State the condensed electron configuration of b. S^2- (sulfur anion)
    [Ne]3s^2 3p^6
  • How many carbons are there in methyl butanoate
    5
  • When an electron falls to a lower energy level it:
    Emits light
  • . Calculate E°cell for the following reaction: 2Fe2+ (aq) + Cd2+ (aq) à 2Fe3+ (aq) + Cd(s)
    -1.17V
  • name an isomer of 2-methylpropane
    butane
  • Identify the following atom from the electron configurations. Y : 1s22s22p63s23p64s23d104p65s24d105p1
    Indium
  • For the reaction: Ag+ (aq) + Cl-(aq) <--> AgCl(s) ΔH = -127kJ/mol In which direction does the equilibrium shift as a result of adding NaCl?
    left
    no change
    to the right
  • Using the following thermochemical data: 2Y(s) + 6HF(g) → 2YF3(s) + 3H2(g) ΔH° = –1811.0 kJ/mol 2Y(s) + 6HCl(g) → 2YCl3(s) + 3H2(g) ΔH° = –1446.2 kJ/mol calculate ΔH° for the following reaction: YF3(s) + 3HCl(g) → YCl3(s) + 3HF(g)
    182.4 kJ/mol
  • If you have a negative entropy and a positive enthalpy, what can the Gibb's free energy be?
    only positive
  • Identify the following atom or ion from the electron configurations. Y - : 1s22s22p63s23p64s23d104p65s24d105p6
    Iodine anion
  • Given the equilibrium: AgBr(s) <--> Ag+ (aq) + Br-(aq) Ksp = 3.3 x 10-13 If [Br-(aq)] = 0.50 mol/L, what is [Ag+ (aq)]?
    6.6 x 10^-13
  • What is the major product when 2-methylprop-1-ene is treated with HBr at room temperature?
    2-bromo-2-methylpropane
  • For nitrous acid, HNO2, Ka = 4.0 × 10–4. Calculate the pH of 0.54 M HNO2.
    1.83
  • Which of the following is NOT a strong base? 1. Be(OH)2 c. NaOH 2. Li2O d. CaO
    Be(OH)2
  • What is the name of this compound?
    2-bromo-1,3-dimethylbenzene
  • For the reaction: 2HI (g) <--> H2 (g) + I2 (g). If the Ksp is 0.020 and the Qsp is 0.34, the reaction will proceed which direction?:
    Proceed to the left
  • What VSEPR molecular shape do you expect for IF4 +?
    square planar
    octahedral
    tetrahedral
    seesaw
  • Calculate the [H+] in a solution that has a pH of 9.48.
    3.3 × 10–10 M