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IB HL Intermolecular Forces

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    Intermolecular Forces, Shapes of Molecules, VSEPR
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  • Explain why HCl is more soluble in water than Cl2.
    HCl is a polar molecule (forms ion-dipole interaction with water) while Cl2 is non polar
  •  10
  • Explain why the melting point of HF does not follow the trend of the other hydrogen halides.
    HF has hydrogen bonding as its main IMF; while HCl, HBr, HI have dipole-dipole which is a generally weaker IMF than Hydrogen bonding
  •  10
  • Why is the melting point of HI higher than HBr?
    HI has greater molar mass (more electrons) and so it has stronger dispersion forces than HBr
  •  10
  • Explain why pure carbon has a melting point of approximately 3550C while pure nitrogen has a melting point of -210C.
    Carbon = giant covalent structure = strong bonding; N2 molecule = weak dispersion forces between particles = requires lesser energy to separate them
  •  15
  • State the electron domain, molecular shape, bond angle/s and polarity: CH4
    4, tetrahedral, 109.5, non-polar
  •  15
  • State the electron domain, molecular shape, bond angle/s and polarity: H2S
    4, bent, 104.5, polar
  •  15
  • State the electron domain, molecular shape, bond angle/s and polarity: PH3
    4, trigonal pyramidal, 107, polar
  •  15
  • State the electron domain, molecular shape, bond angle/s and polarity: BF3
    3, trigonal planar, 120, non-polar
  •  15
  • State the electron domain, molecular shape, bond angle/s and polarity: BeI2
    2, linear, 180, non-polar
  •  15
  • State the electron domain, molecular shape, bond angle/s and polarity: SO3
    3, trigonal planar, 120, non-polar
  •  15
  • State the electron domain, molecular shape, bond angle/s and polarity: SO2
    3, bent, 117.5, polar
  •  15
  • State the electron domain, molecular shape, bond angle/s and polarity: HCN
    2, linear, 180, polar
  •  15
  • State the electron domain, molecular shape, bond angle/s and polarity: [NH4]+
    4, tetrahedral, 109.5, non-polar
  •  15
  • State the electron domain, molecular shape, bond angle/s and polarity: [CO3]2-
    3, trigonal planar, 120, non-polar
  •  15
  • State the electron domain, molecular shape, bond angle/s and polarity: CH2O
    3, trigonal planar, 120, polar
  •  15
  • Give an example of a substance that is very soluble in water and has a pyramidal shape.
    (answers may vary - NH3, PH3, ...)
  •  10