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grade 12 Chemistry review
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How many electrons in an atom can have the quantum numbers n = 3, l = 2?
10
18
2
8
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When ignited, a uranium compound burns with a green flame. The wavelength of the light given off by this flame is greater than that of
UV
radio waves
red light
microwaves
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What is the percent dissociation of HNO2 when 0.058 g of sodium nitrite is added to 110.0 mL of a 0.060 M HNO2 solution? Ka for HNO2 is 4.0 × 10–4.
5.2%
13%
0.31%
8.2%
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Calculate the [H+] in a solution that is 0.18 M in NaF and 0.25 M in HF. (Ka = 7.2 × 10–4)
1.0 × 10–3 M
7.2 × 10–4 M
5.2 × 10–4 M
0.020 M
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Find the rate equation:
Rate = k[A]3
Rate = k[A]2[B]2
Rate = k[A][B]
Rate = k[A][B]2
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Which type of alcohols are oxidized to produce carboxylic acids?
primary
secondary
tertiary
quaternary
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Consider the reaction X → Y + Z Which of the following is a possible rate law?
Rate = k[X]
Rate = k[Y]
Rate = k[Y][Z]
Rate = k[X][Y]
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For the reaction 2A + 4B→2C + 2D, at a particular instant in time, the rate of the reaction is 0.0352 M/s. What is the rate of change of B?
–0.141 M/s
–0.0352 M/s
0.141 M/s
0.0352 M/s
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Consider an electrochemical cell with a zinc electrode immersed in 1.0 M Zn2+ and a silver electrode immersed in 1.0 M Ag+.
1.560 V
-1.560 V
-0.040 V
0.040 V
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You are told that metal X is a better reducing agent than metal Y. This must mean that:
Y+ is a better oxidizing agent than X+.
X+ is a better reducing agent than Y+.
X+ is a better oxidizing agent than Y+.
Y is a better oxidizing agent than X.
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How many electrons are transferred in the following reaction? Cd + 2HCl → CdCl2 + H2
2
1
4
3
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The following reaction occurs in basic solution: F2 + H2O → O2 + F– When the equation is balanced, the sum of the coefficients is:
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Given the following reaction in acidic media: Fe2+ + Cr2O72– → Fe3+ + Cr3+ answer the following question: The coefficient for water in the balanced reaction is:
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Which of the following would have the highest boiling point?
pentanamine
pentane
pentanal
pentan-2-one
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For nitrous acid, HNO2, Ka = 4.0 × 10–4. Calculate the pH of 0.54 M HNO2.
1.83
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Calculate the [H+] in a solution that has a pH of 9.48.
3.3 × 10–10 M
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The pH at the equivalence point of a titration of a weak acid with a strong base will approximately be
greater than 7.00
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Calculate the [H+] in a solution that is 0.18 M in NaF and 0.25 M in HF. (Ka = 7.2 × 10–4)
1.0 × 10–3 M
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Using the following thermochemical data: 2Y(s) + 6HF(g) → 2YF3(s) + 3H2(g) ΔH° = –1811.0 kJ/mol 2Y(s) + 6HCl(g) → 2YCl3(s) + 3H2(g) ΔH° = –1446.2 kJ/mol calculate ΔH° for the following reaction: YF3(s) + 3HCl(g) → YCl3(s) + 3HF(g)
182.4 kJ/mol
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What is the specific heat capacity of zinc if it requires 146 J to raise the temperature of 15 grams of zinc by 25°C?
0.39 J/g°C
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How can you convert but-2-yne to (2Z)-but-2-ene
specifically a Lindlar hydrogenation (converts to cis configuration)
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What is the VSEPR shape of AsH3
trigonal pyramidal (AX3E)
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name an isomer of 2-methylpropane
butane
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State the condensed electron configuration of b. S^2- (sulfur anion)
[Ne]3s^2 3p^6
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Cyclopropane undergoes rearrangement to form propene, C3H6. If cyclopropane disappears at a rate of 0.50 mol/ Ls, at what rate is propene being pduced?ro
rate of appearance = +0.50 mol/Ls
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What is the hybridization of a carbon in ethene?
sp2
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If you have a negative entropy and a positive enthalpy, what can the Gibb's free energy be?
only positive
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What is the pH of a solution made of 0.50 M acetic acid and 0.200 sodium acetate given the Ka of acetic acid is 1.8 x 10-5?
4.34
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. Calculate E°cell for the following reaction: 2Fe2+ (aq) + Cd2+ (aq) à 2Fe3+ (aq) + Cd(s)
-1.17V
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How many carbons are there in 3-ethylpentane?
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Identify the following atom from the electron configurations. Y : 1s22s22p63s23p64s23d104p65s24d105p1
Indium
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Identify the following atom or ion from the electron configurations. Y - : 1s22s22p63s23p64s23d104p65s24d105p6
Iodine anion
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What VSEPR molecular shape do you expect for IF4 +?
seesaw
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What is the correct electronic configuration of Copper?
[Ar]4s13d10
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If n=2, what is l and ml respectively?
l = 0, 1; ml= -1, 0, +1
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When an electron falls to a lower energy level it:
Emits light
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The air pollutant NO is produced in automobile engines from the high temperature reaction: N2 (g) + O2 (g) D 2NO(g) Keq = 1.7 x 10-3 at 2300K. If the initial concentration of N2 (g) and O2 (g) at 2300K are both 1.40M, what is the concent
1.372 mol/L
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Which of the following is NOT a strong base?
Be(OH)2
NaOH
Li2O
CaO
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Given the equilibrium: AgBr(s) <--> Ag+ (aq) + Br-(aq) Ksp = 3.3 x 10-13 If [Br-(aq)] = 0.50 mol/L, what is [Ag+ (aq)]?
6.6 x 10^-13
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For the reaction: 2HI (g) <--> H2 (g) + I2 (g). If the Ksp is 0.020 and the Qsp is 0.34, the reaction will proceed which direction?:
Proceed to the left
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For the reaction: Ag+ (aq) + Cl-(aq) <--> AgCl(s) ΔH = -127kJ/mol In which direction does the equilibrium shift as a result of adding NaCl?
to the right
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What is the major product when 2-methylprop-1-ene is treated with HBr at room temperature?
2-bromo-2-methylpropane
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Is cyclopentanol a primary secondary or tertiary alcohol?
secondary alcohol ( 2 carbons attached to the adjacent carbon of alcohol)
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What is the name of this compound?
2-bromo-1,3-dimethylbenzene
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Which of the following would you expect to have the highest boiling point? ethanol, ethyl ethanoate, ethanoic acid, ethane, ethene, ethyne, ethanal or chloroethane?
ethanoic acid - has the most hydrogen bonding therefore it takes more ENERGY to break those intermolecular bonds. Therefore it should have highest boiling point
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How many carbons are there in methyl butanoate
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Which one of the following is a redox reaction? a) 2KBr(aq) + Pb(NO3 )2 (aq) → 2KNO3 (aq) + PbBr2 (s) b) 2Al(s) + 3H2SO4 (aq) → Al2 (SO4 )3 (aq) + 3H2 (g) c) CaBr2 (aq) + H2SO4 (aq) → CaSO4 (s) + 2HBr(g) d) H+ (aq) + OH– (aq) → H2O(l)
b) 2Al(s) + 3H2SO4 (aq) → Al2 (SO4 )3 (aq) + 3H2 (g)
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Identify the reducing agent in the following chemical reaction. Cd + NiO2 + 2H2O → Cd(OH)2 + Ni(OH)2
Cd
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In the following chemical reaction the oxidizing agent is 1. 5H2O2 + 2MnO4 – + 6H+ → 2Mn2+ + 8H2O + 5O2
MnO4 –
H2O2
Mn2+
O2
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The oxidation number of Fe in K3Fe(CN)6 is:
+3
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The oxidation number of N in (NH4)3PO4 (ammonium phosphate) is:
-3
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