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Chemical Bonds HL
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calcium phosphate [OR calcium phosphate (V)]
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How is the electron domain geometry of ammonia related to the hybridization of the N atom?
sp3 hybridization produces a tetrahedral electron domain
sp3 hybrid produces a trigonal pyramidal electron domain
sp2 hybridization produces a tetrahedral electron domain
sp2 hybrid produces a trigonal pyramidal electron domain
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Which hybridization is being depicted in this valence electron configuration shown here?
sp2
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a) what is the hybridization of bonds? b)What is the bond order?
electron and molecular geometry is trigonal planar. It is sp2 hybridized and it has a bond order of 1.33
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Which hybridization is depicted in the molecule shown here?
sp3
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Which hybridization is depicted in the molecule shown here?
sp
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Which of the following has a pure covalent bond?
H2
CO2
CCl4
H2O
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What name is given to a compound composed of two non-metals?
Molecular
Alloy
Ionic
Polyatomic ions
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State the intermolecular forces present in all of the halogens in their standard states.
London Dispersion Forces (Dispersion forces)
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In paper chromatography, components of a mixture are separated according to which property?
Solubility
Melting point
Electronegativity
Intramolecular forces
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A white solid has a melting point of 2072 ∘ C 2072 ∘ C. It does not conduct electricity in the solid state, but does so in the molten state. Which type of structure is found in the solid material?
ionic
simple molecular
giant molecular
metallic
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The molecule of oxygen contains one σ and one π bond. How do p orbitals in the O atoms overlap to produce the π bond?
Sideways overlap results in high electron density above and
End-to-end overlap results in high electron density above an
Sideways overlap results in high electron density along the
End-to-end overlap results in high electron density along th
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Consider the skeletal structure shown below: N—C—C—N Draw the Lewis structure and answer the following: How many of the atoms are sp hybridized?
4
3
2
1
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what is the bond order of carbonate ion?
1.33
1.5
1.67
1.25
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The hybridization of I in IF4– is
d2sp3
dsp3
sp3
sp2
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The hybridization of the central atom in XeF5+ is:
d2sp3
dsp3
sp3
sp2
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A trigonal bipyramidal molecule contains what hybridization
dsp3
sp
sp3
sp2
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A trigonal planar molecule contains what hybridization
sp2
sp
sp3
dsp3
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In the molecule C2H4 the valence orbitals of the carbon atoms are assumed to be
sp2 hybridized
sp hybridized
sp3 hybridized
not hybridized
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Which statements regarding alloys are correct?
I and III only
I, II and III
I and II only
II and III only
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Which compound contains both ionic and covalent bonds?
NaNO3
H2CO
SiH4
Na2O
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Which compound has the shortest C–N bond?
CH3CN
(CH3)3CNH2
CH3NH2
CH3CHNH
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Which of the following does NOT hydrogen bond?
CH3F
CH3NH2
CH3OH
HF
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Which of the following best describes the changes that Which of the following best describes the changes that occur in the forces of attraction between CO2 molecules as they change phase from a gas to a solid?
London (dispersion) forces operate to form the solid
C-O bonds are formed
CO2 molecules crystallize around a nucleation point
Ionic bonds between CO2 molecules are formed
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Which of the following molecules has a dipole moment?
NF3
SiH4
BCl3
F2
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How many resonance structures are there of ozone?
2
1
3
4
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In the cyanide ion (CN–), the nitrogen has a formal charge of
0
+2
-2
-1
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Which of the following would you expect to have the highest melting point?
iodine
bromine
chlorine
fluorine
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Which of the following molecules contains a double bond?
carbon dioxide
ammonia
water
hydrogen fluoride
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Which of the molecules obeys the octet rule?
O3
PCl5
BH3
NO2
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In the gaseous phase, which of the following diatomic molecules would be the most polar?
CsF
CsCl
NaCl
LiF
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Atoms with greatly different electronegativity values are expected to form
ionic bonds
triple bonds
double bonds
no bonds
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In which pair do both compounds exhibit predominantly ionic bonding?
RbCl and MgS
BaF and H2O
Na2SO3 and NH3
SCl4 and HF
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What is the electron geometry, molecular geometry and bond angles in PF3. Is it polar?
electron = tetrahedral; molecular = trigonal pyramidal. angles - <109.5; polar
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Name all the intermolecular forces in HCl
dipole-dipole and LDF only
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Which intermolecular force does NOT exist when KF is dissolved in NH3?
ion-induced dipole
ion-dipole
hydrogen bond
dipole-dipole
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What is the electron and molecular geometry of chlorate ion? Is it polar?
Electron: tetrahedral. Molecular : Trigonal pyramidal. : It is polar because it is both asymmetric and it is an anion. (draw please w lone pair on chlorinei
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Why is CHCl3 more polar than CCl4?
CCl4 is symmetric and therefore no net dipole; CHCl3 is asymmetric
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What is the electron and molecular geometry for carbon dioxide. From this data, is it polar?
Electron: linear. Molecular: linear. - It is symmetric therefor NOT POLAR
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Which molecule is most polar?
CHF 3
CF 4
CCl 4
CClF 3
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The Lewis (electron dot) structure of the ethanedioate ion is shown. Outline why all the C–O bond lengths in the ethanedioate ion are the same length
electrons delocalized «across the O–C–O system» or RESONANCE
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Which series shows the correct order of metallic bond strength from strongest to weakest?
Mg > Na > K > Rb
Rb > K > Na > Mg
Mg > Rb > K > Na
Na > K > Rb > Mg
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What is the molecular geometry of the carbonate ion? What would be the angles?
trigonal planar; 120 degrees
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Best explanation here that graphite is softer than diamond
layers can slide/move
graphite is in a tetrahedral arrangement
every carbon atom has a strong bond to the other
the carbons have 4 bonds
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What would be the best use of graphite?
electrode
lubricant because it is soft and slippery with weak forces
used in drill heads
decorative stone for rings
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Give at least 2 (two) ways to refer to this adorable looking allotrope of carbon
any 2: Bucky ball OR C-60 OR fullterene OR buckminsterfullerene
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How many covalent bonds does graphite have?
3
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Why do ionic solids NOT conduct electricity?
This is due to the fact that ions are not free to move in a solid as they are arranged in an ionic lattice.
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Which of the following would you expect to have the highest melting point?
magnesium fluoride
dinitrogen oxide
phosphorous trichloride
hydrogen chloride
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What do sodium ions have in common with chloride ions?
they both have the same sized charge
they are both cations
they are both anions
they both form covalent bonds
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What is the arrangement of the bonds in diamond as shown in this structure?
tetrahedral - (4 bonds each 109.5 degrees apart)
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Which of the following is the definition of an allotrope?
2 or more different physical forms in which an element exist
The same chemical formula but a different structure
Different numbers of neutrons but same protons
Different states of a compound
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What is the formula for the compound potassium sulfate?
K2SO4
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What is the suffix for all binary ionic compounds of representative elements?
-ide
-ite
-ate
-gen
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Charlie claims that a single sodium ion and a single oxygen ion do not bond together to form a stable binary ionic compound. Is he correct? You must explain completely
Charlie is correct. The sum of the charges of the two ions must be zero in order for them to form a stable ionic compound.
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What is the chemical formula for diamond?
C(s)
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In the formation of the compound of sodium chloride
a sodium atom donates an electron to a chlorine atom
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Covalent bonds take place between
two nonmetals
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Which rule must be fulfilled by sharing or transferring electrons to create bonds in order for an element to be stable?
octet rule
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What will the result be when a reaction between bismuth and fluorine takes place?
BiF3
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Which pairs of words correctly completes the statement? Ionic compounds form when____ and _____ react.
metals ; nonmetals
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Unknown element W has 2 valence electrons. Unknown element X has 7 valence electrons. Which formula shows the most likely outcome when elements W and X react?
WX2
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What is the name of the compound Ni(NO3)2
Nickel (II) nitrate
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What is the chemical formula for the compound barium bromide?
BaBr2
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What is the name of the compound SrSO4
strontium sulfate
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What is the sum of the charges in a compound?
0
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A chemical formula includes the symbols of the elements in the compound and subscripts that indicate
the number of atoms or ions of each type
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What is the metallic ion in the compound CuCl2?
Cu2+
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Calcium (Ca) is in the second column of the periodic table and is classified as an alkaline earth metal. Which of the following formulas shows the ratio of a compound formed from calcium and iodine(I)?
CaI2
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What is the formula for the compound formed when a potassium ion(K+) and a sulfide ion (S-2) unite?
K2S
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what is the formula of aluminum carbonate?
Al2(CO3)3
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What is the chemical formula for calcium oxide?
CaO
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What is the formula for the compound formed when aluminum ions(Al 3+) and chloride ions (Cl -) unite?
AlCl3
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