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Harris Quantitative Analysis Chapter 10

  •  English    10     Public
    Polyprotic Acids/Bases
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  • Which equation shows the correct relationship between the Ka and Kb values for a diprotic species?
    Ka1 × Ka2 = Kw
    Ka1 × Kb1 = Kw
    Kb1 × Kb2 = Kw
    Ka1 × Kb2 = Kw
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  • (T or F) The following reaction is an example a hydrolysis reaction: L− + H2O<====>HL + OH−
    True
    False
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  • (T or F) For most diprotic species, the acidic (H2A) and basic (A2−) forms can be treated as monoprotic species when calculating the pH of a solution.
    False
    True
  •  15
  • What is the pH of a 0.100 M maleic acid (pK1 = 1.89, pK2 = 6.23) solution?
    1.23
    1.52
    8.50
    5.74
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  • (T or F)A buffer made from a diprotic acid is treated in the same way as a buffer made from a monoprotic acid.
    False
    True
  •  15
  • Which of the following is FALSE for an aqueous solution of the weak acid H3A?
    A^3− is acidic.
    HA2− is amphiprotic.
    HA^2-
    H3A is acidic.
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  • Which one of the following pairs cannot be mixed together to form a buffer solution?
    KOH, HF
    RbOH, HBr
    NaC2H3O2, HCl (NaC2H3O2 = acetate)
    H3PO4, KHPO4
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  • 10 The Ka of acetic acid is 1.7 *10-5 The pH of a buffer prepared by combining 50.0 mL of 1.00 M potassium acetate and 50.0 mL of 1.00 M acetic acid is __________.
    9.26
    9.37
    4.77
    7
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  • What is the principal form of benzoic acid at pH = 3.00?
    Benzoic Acid
    Benzoate
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  • What is the principal form of benzoic acid at pH = 6.00?
    Benzoic Acid
    Benzoate
  •  15