Explain the following trend in boiling points: CH4 < C2H6 < C3H8
All molecules are nonpolar = only dispersion forces = increase in mass = stronger dispersion forces = higher BP
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15
State the electron domain, molecular shape, bond angle/s and polarity: H2S
4, bent, 104.5, polar
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15
Explain why polar molecules are often soluble in water while non-polar molecules are not. Include discussion on the intermolecular processes involved in dissolving.
soluble = IMF solute and IMF solvent are similar; water is polar = h-bonding and dipole dipole; nonpolar solute = dispersion (way weaker than IMF in solvent)
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10
Explain why the melting point of HF does not follow the trend of the other hydrogen halides.
HF has hydrogen bonding as its main IMF; while HCl, HBr, HI have dipole-dipole which is a generally weaker IMF than Hydrogen bonding
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10
Give the two common materials used in TLC as the stationary phase
Alumina (Al2O3) and Silica (SiO2)
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15
State the electron domain, molecular shape, bond angle/s and polarity: SO3
3, trigonal planar, 120, non-polar
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15
State the electron domain, molecular shape, bond angle/s and polarity: CH2O
3, trigonal planar, 120, polar
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10
Give an example of a substance that has a very high 1st ionization energy, a very low BP and does not form bonds.
(answers may vary - any noble gas)
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15
State the electron domain, molecular shape, bond angle/s and polarity: [NH4]+
4, tetrahedral, 109.5, non-polar
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15
State the electron domain, molecular shape, bond angle/s and polarity: [CO3]2-
3, trigonal planar, 120, non-polar
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15
Explain why CO is polar while CO2 is nonpolar.
O is more EN than C; CO has uneven distribution of e in bond, thus polar; CO2 is linear (symmetrical), charge distribution is even, thus non-polar
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15
Explain why pure carbon has a melting point of approximately 3550C while pure nitrogen has a melting point of -210C.
Carbon = giant covalent structure = strong bonding; N2 molecule = weak dispersion forces between particles = requires lesser energy to separate them